Search results for "Constant current"
showing 10 items of 11 documents
Unexpected high robustness of electrochemical cross-coupling for a broad range of current density
2017
Solvent effect enables electrosynthesis of organic compounds with strong variation of electric current at constant efficacy.
Electrochemical synthesis of benzoxazoles from anilides - a new approach to employ amidyl radical intermediates.
2017
A novel electrochemical method for the synthesis of benzoxazoles from readily available anilides is reported. Various functionalities are tolerated and good yields can be achieved. By employing common electrode materials and a simple constant current protocol, this method is an attractive new alternative to conventional pathways.
Simple electrochemical reduction of nitrones to amines.
2018
Only electricity is needed for the transformation of nitrones to amines. Such a direct double reduction has not been reported by any sole chemical reagent in a single step process.
Simple and scalable electrochemical synthesis of 2,1-benzisoxazoles and quinoline N-oxides.
2019
Cathodic reduction of the nitro moiety and subsequent intramolecular cyclization affords different substituted 2,1-benzisoxazoles and quinoline N-oxides. This methodology allows the synthesis of two different types of heterocycles from common simple starting materials, using electrons as a sole reagent for this transformation. The electrolysis can be conducted in a very simple undivided electrolysis cell under constant current conditions. This permits working on a larger scale compared to other electrochemical methodologies and represents a significant advantage.
A Non-Invasive Thermal Drift Compensation Technique Applied to a Spin-Valve Magnetoresistive Current Sensor
2011
A compensation method for the sensitivity drift of a magnetoresistive (MR) Wheatstone bridge current sensor is proposed. The technique was carried out by placing a ruthenium temperature sensor and the MR sensor to be compensated inside a generalized impedance converter circuit (GIC). No internal modification of the sensor bridge arms is required so that the circuit is capable of compensating practical industrial sensors. The method is based on the temperature modulation of the current supplied to the bridge, which improves previous solutions based on constant current compensation. Experimental results are shown using a microfabricated spin-valve MR current sensor. The temperature compensati…
Design and experimental verification of a smart sensor to measure the energy and power consumption in a one-phase AC line
2009
Abstract A mixed electronic system has been designed to measure the active, apparent and reactive energies delivered to a load in a single-phase AC voltage line. For this purpose a smart sensor (ADE7753 from Analog Devices) was used. A magnetoresistance sensor is used as a current transducer and it is constant current biased by a generalized impedance converter. The magnetoresistance sensor technology provides direct isolation from the mains voltage and ferrite cores are not needed like Hall counterparts. All the measurements provided by the ADE7753 are read through the parallel port of the computer using a LabView application, which will process and present the readings to the user.
A new backward/forward method for solving radial distribution networks with PV nodes
2008
Abstract In this paper, a new backward/forward (b/f) methodology for the analysis of distribution systems with constant power loads is presented. In the proposed method, at each iteration, the loads are considered as constant impedances; in the backward sweep all the network variables (bus voltages and branch currents) are evaluated considering a scaling factor which is determined at the end of the backward phase. Indeed the forward sweep is eliminated and the node voltages calculation does not demand the sequentiality needed in the b/f methodology. The developed method, although deriving conceptually from the b/f methodology, presents only the backward phase in which all the network variab…
Synthesis of Highly Functionalized N , N ‐Diarylamides by an Anodic C, N ‐Coupling Reaction
2019
We report an innovative, sustainable and straightforward protocol for the synthesis of N,N-diarylamides equipped with nonprotected hydroxyl groups by using electrosynthesis. The concept allows the application of various substrates furnishing diarylamides with yields up to 57 % within a single and direct electrolytic protocol. The method is thereby easy to conduct in an undivided cell with constant current conditions offering a versatile and short-cut alternative to conventional pathways.
A deep-blue emitting charged bis-cyclometallated iridium(iii) complex for light-emitting electrochemical cells
2013
We report here a new cationic bis-cyclometallated iridium(III) complex, 1, with deep-blue emission at 440 nm and its use in Light-emitting Electrochemical Cells (LECs). The design is based on the 2′,6′-difluoro-2,3′-bipyridine skeleton as the cyclometallating ligand and a bis-imidazolium carbene-type ancillary ligand. Furthermore, bulky tert-butyl substituents are used to limit the intermolecular interactions. LECs have been driven both at constant voltage (6 V) and constant current (2.5 mA cm−2). The performances are significantly improved with the latter method, resulting overall in one of the best reported greenish-blue LECs having fast response (17 s), light intensity over 100 cd m−2 an…
Study of voltage decrease in organic light emitting diodes during the initial stage of lifetime
2016
Abstract We report the results of lifetime DC testing at constant current of not-encapsulated organic light emitting diodes (OLEDs) based on Tris (8 idroxyquinoline) aluminum (Alq3) as emitting material. In particular, a voltage decrease during the initial stage of the lifetime test is observed. The cause of this behavior is also discussed, mainly linked to initial Joule self-heating of the device, rising its temperature above room temperature until thermal equilibrium is reached at steady state.